rearrangement

1.The method of liquid phase rearrangement of styrene oxide to phenylacetaldehyde catalyzed by SAStype solid acids and molecular sieves was studied.

研究SAS型固体酸几种分子筛上氧化苯乙烯液相重排成苯乙醛的反应,考察催化剂的活性、选择性定性。

2.The rearrangement of acetone oxime in the Beckmann solution involves three acetic acid molecules and one proton (present as an oxonium ion).

模拟表明，有三个乙酸分子一个质子（以氧鎓的形式纯在）参与反应。

3.Citral was synthesized by catalytical rearrangement of dehydrolinalool in toluene solution with the present of molybdenyl acetylacetonate, benzoic acid and dimethyl sulfoxide (DMSO).

摘要采用脱氢芳樟醇为原料，在乙酰丙酮酸钼、苯甲酸、二甲基亚砜(DMSO)的甲苯溶液中催化重排合成柠檬醛，考察柠檬醛在不同体系中的热敏性。